Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff          下载免费PDF全文

Chuan‐An Xia  Juxiu Tong  Bill X. Hu  Xiujie Wu  Alberto Guadagnini 《水文研究》2018,32(20):3140-3157

We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AIC_C] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component.  相似文献   

敦煌-格尔木铁路沿线风动力环境特征     

鱼燕萍  张克存  安志山  张余 《中国沙漠》2020,40(1):41-48

敦煌-格尔木铁路沿线地形复杂、起沙因素多变、沙源丰富，沙害问题日益严重。目前对其风沙活动规律还未有研究，不利于防沙工作的开展。为此，通过对自北向南的5个观测点（S1、S2、S3、S4、S5）风速和风向的观测、计算和分析，利用平均风速、起沙风况及输沙势对敦格铁路沿线的风动力环境特征进行研究。结果表明：S5、S4和S3的风况对铁路风沙灾害防治意义较大。S5年平均风速、起沙风频率和输沙势最大，春季风沙活动最为强烈，且风向单一、风力强劲，风沙运动方向基本与铁路垂直，沙粒易在铁路附近堆积。S4夏季风沙活动最为强烈；S3春季风沙活动最为强烈，且风向单一，S4和S3的风沙运动方向与铁路夹角小于90°，附近沙源广阔，铁路易受风沙侵蚀，阻碍交通运营。  相似文献   

一种基于自证明公钥的可公开验证的认证加密方案     

彭银桥  甘元驹  邓锐  彭凌西  陈月峰 《广东海洋大学学报》2005,25(3):73-75

针对现有的基于证书的认证加密方案通信量和计算量大的缺点,提出了基于自证明公钥的可公开验证的认证加密方案。详细阐述了方案的系统初始化、签名生成、消息恢复验证以及公开验证4个阶段,方案的安全性是基于求解离散对数的困难性(DLP)和强单向hash函数(OWFH)的不可逆。该方案在没有签名者的协作下,任何验证者都可验证签名者的诚实性,在验证签名的同时可认证签名者的公钥,因而减少了存储空间、通信量和计算量。  相似文献   

一种基于Ohta-Okamoto签名的门限群签名方案     

彭银桥  甘元驹  陈月峰  彭凌西  邓锐 《广东海洋大学学报》2005,25(4):76-78

在修改的Ohta_Okamoto数字签名方案基础上,设计出了一个新的(t,n)门限签名方案。该方案具有可验证性和防止内部成员合谋攻击;而且验证者在验证群签名的有效性计算的复杂性与一般个人签名方案一样。该方案的安全性是基于大整数的因式分解,因此在计算上是安全的。  相似文献   

The nature of parallax microlensing events towards the Galactic bulge     

Martin C. Smith  Vasily Belokurov  N. Wyn Evans  Shude Mao  Jin H. An 《Monthly notices of the Royal Astronomical Society》2005,361(1):128-140

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论现代航海技术与高等航海教育     

邓礼标 《广东海洋大学学报》2004,24(5):126-130

针对航海技术的现状和发展趋势 ,提出了高等航海教育应向国际化、高素质化、现代化、技能化、规范化发展 ,以培养高素质的国际航运人才。  相似文献   

Study on Application of Polyenzyme Method to Offal of Harengula zunasi     

邓尚贵  杨萍  夏杏洲 《中国海洋湖沼学报》2003,21(4):312-318

The new polyenzyme method for making gravy from Harengula zunasi offal involves protein enzymolysis with flavorase after proper alkaline and neutral protease levels were established by orthogonal trials to select the best hydrolytic conditions for processing offal with alkaline and neutral protease. The conditions for the polyenzyme method were pH of 7.0, temperature of 50℃ , alkaline and neutral protease concentration of 1.5% respectively, hydrolysis time of 120 min, andflavorase concentration of 2.0% , for 60 min. The new gravy-making technology yields a nutritious and delicious gravy containing 40.3 % of total essential amino acids, with delicious amino acids Glu, Asp, Gly, Ala, Pro and Ser comprising 49.5% , total and amino nitrogen being respectively1.9 and 1.1 g/100 g (amino acid nitrogen being 61.0% of total nitrogen), The polyenzyme method was used to make 14.8% protein gravy from Harengula zunasi offal. In addition, in inorganic elements, the phosphorus content is the highest.  相似文献   

基于NiosⅡ嵌入式软核处理器的天文用IRFPA图像采集系统     

邱志强  邓建  叶彬浔 《天文研究与技术》2006,3(4):373-379

介绍了一套自主研制的用于地基天文望远镜的，基于IRFPA（红外焦平面阵列）图像采集系统，以及所使用的IRFPA原理、性能特点，着重介绍了IRFPA图像采集系统中以NiosⅡ处理器为核心的电子系统的框架结构方案以及软硬件的设计思想。最后给出了初步的图像采集成像结果。  相似文献   

Modeling the distribution of aluminum speciation in acid soil solution equilibria with the mineral phase alunite     

S. Bi  S. An  W. Tang  M. Yang  H. Qian  J. Wang 《Environmental Geology》2001,41(1-2):25-36

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单片机在卫星天线控制系统中的应用     

樊昌元  邓洪 《成都信息工程学院学报》2005,20(1):41-44

主要介绍卫星天线控制系统中天线旋转定位控制的软硬件设计和实现。该部分的主要功能是：接收红外遥控器的信号；检测前面板上的按键信号；检测传感器反馈的信号；根据所得信号作出相应的动作。  相似文献